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Crystal structures of N '-amino-pyridine-2-carboximidamide and N '-{[1-(pyridin-2-yl)ethyl-idene]amino}-pyridine-2-carboximidamide.
- Source :
-
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2017 Jun 13; Vol. 73 (Pt 7), pp. 1021-1025. Date of Electronic Publication: 2017 Jun 13 (Print Publication: 2017). - Publication Year :
- 2017
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Abstract
- The crystal structures of N '-amino-pyridine-2-carboximidamide (C <subscript>6</subscript> H <subscript>8</subscript> N <subscript>4</subscript> ), 1 , and N '-{[1-(pyridin-2-yl)ethyl-idene]amino}-pyridine-2-carboximidamide (C <subscript>13</subscript> H <subscript>13</subscript> N <subscript>5</subscript> ), 2 , are described. The non-H atoms in compound 1 are nearly planar (r.m.s. deviation from planarity = 0.0108 Å), while 2 is twisted about the central N-N bond by 17.8 (2)°. Both mol-ecules are linked by inter-molecular N-H⋯N hydrogen-bonding inter-actions; 1 forms a two-dimensional hydrogen-bonding network and for 2 the network is a one-dimensional chain. The bond lengths of these mol-ecules are similar to those in other literature reports of azine and di-imine systems.
Details
- Language :
- English
- ISSN :
- 2056-9890
- Volume :
- 73
- Issue :
- Pt 7
- Database :
- MEDLINE
- Journal :
- Acta crystallographica. Section E, Crystallographic communications
- Publication Type :
- Academic Journal
- Accession number :
- 28775873
- Full Text :
- https://doi.org/10.1107/S2056989017008416