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Crystal Growth and Characterization of HgBa 2 Ca 2 Cu 3 O 8+δ Superconductors with the Highest Critical Temperature at Ambient Pressure.
- Source :
-
Inorganic chemistry [Inorg Chem] 2017 Aug 21; Vol. 56 (16), pp. 9396-9399. Date of Electronic Publication: 2017 Aug 10. - Publication Year :
- 2017
-
Abstract
- We report an original procedure for the elaboration of very high-quality single crystals of superconducting HgBa <subscript>2</subscript> Ca <subscript>2</subscript> Cu <subscript>3</subscript> O <subscript>8+δ</subscript> mercury cuprates. These single crystals are unique, with very high-quality surface paving the way for spectroscopic, transport, and thermodynamic probes in order to understand the hole-doped cuprate phase diagram. Annealing allows one to optimize T <subscript>c</subscript> up to T <subscript>c</subscript> <superscript>max</superscript> = 133 K. The superconductivity transition width of about 2 K indicates that they are homogeneous. We show for the first time that, with adequate heat treatment, Hg-1223 can be largely underdoped and its doping level controlled. Importantly, the crystal structure was studied in detail by single-crystal X-ray diffraction, and we have identified the signature of the underdoping by a detailed sample characterization and micro-Raman spectroscopy measurements.
Details
- Language :
- English
- ISSN :
- 1520-510X
- Volume :
- 56
- Issue :
- 16
- Database :
- MEDLINE
- Journal :
- Inorganic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 28796493
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.7b01372