An arsenate with the α-CrPO 4 structure type, NaCa 1-x Ni 3-2x Al 2x (AsO 4 ) 3 (x = 0.23): crystal structure, charge-distribution and bond-valence-sum analyses.

Since the discovery of electrochemically active LiFePO ₄ , materials with tunnel and layered structures built up of transition metals and polyanions have become the subject of much research. A new quaternary arsenate, sodium calcium trinickel aluminium triarsenate, NaCa _1-x Ni _3-2x Al _2x (AsO ₄ ) ₃ (x = 0.23), was synthesized using the flux method in air at 1023 K and its crystal structure was determined from single-crystal X-ray diffraction (XRD) data. This material was also characterized by qualitative energy-dispersive X-ray spectroscopy (EDS) analysis and IR spectroscopy. The crystal structure belongs to the α-CrPO ₄ type with the space group Imma. The structure is described as a three-dimensional framework built up of corner-edge-sharing NiO ₆ , (Ni,Al)O ₆ and AsO ₄ polyhedra, with channels running along the [100] and [010] directions, in which the sodium and calcium cations are located. The proposed structural model has been validated by bond-valence-sum (BVS) and charge-distribution (CHARDI) tools. The sodium ionic conduction pathways in the anionic framework were investigated by means of the bond-valence site energy (BVSE) model, which predicted that the studied material will probably be a very poor Na ⁺ ion conductor (bond-valence activation energy ∼7 eV).