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Unexpected Synthesis of a Bulky Bis-Pocket A₃B-Type Meso-Cyano Porphyrin.

Authors :
Liu ZY
Mahmood MH
Wu JZ
Yang SB
Liu HY
Source :
Molecules (Basel, Switzerland) [Molecules] 2017 Nov 09; Vol. 22 (11). Date of Electronic Publication: 2017 Nov 09.
Publication Year :
2017

Abstract

A one-pot synthesis of bulky bis-pocket A₃B-type meso -cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.<br />Competing Interests: The authors declare no conflict of interest.

Details

Language :
English
ISSN :
1420-3049
Volume :
22
Issue :
11
Database :
MEDLINE
Journal :
Molecules (Basel, Switzerland)
Publication Type :
Academic Journal
Accession number :
29120395
Full Text :
https://doi.org/10.3390/molecules22111941