Back to Search
Start Over
Unexpected Synthesis of a Bulky Bis-Pocket A₃B-Type Meso-Cyano Porphyrin.
- Source :
-
Molecules (Basel, Switzerland) [Molecules] 2017 Nov 09; Vol. 22 (11). Date of Electronic Publication: 2017 Nov 09. - Publication Year :
- 2017
-
Abstract
- A one-pot synthesis of bulky bis-pocket A₃B-type meso -cyano porphyrin, 5-cyano-10,15,20-tris(2,4,6-triphenylphenyl)porphyrin, has been accomplished via trifluoroacetic acid (TFA) catalyzed condensation of pyrrole and 2,4,6-triphenylbenzaldehyde in an acceptable yield of about 4%. DDQ served as oxidant and the cyanating agent.<br />Competing Interests: The authors declare no conflict of interest.
Details
- Language :
- English
- ISSN :
- 1420-3049
- Volume :
- 22
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Molecules (Basel, Switzerland)
- Publication Type :
- Academic Journal
- Accession number :
- 29120395
- Full Text :
- https://doi.org/10.3390/molecules22111941