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From helix to helical pores: solid-state crystalline conversions triggered by gas-solid reactions.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2017 Nov 30; Vol. 53 (96), pp. 12950-12953. - Publication Year :
- 2017
-
Abstract
- Two one-dimensional (1D) helical coordination polymers, CuBIm-Cl and CuBIm-Br (BIm = 1,2-bis((5H-imidazol-4-yl)-methylene)hydrazine), are constructed from Cu <superscript>2+</superscript> ions, halides and mono-deprotonated BIm. Solid-state crystalline conversions of CuBIm-Cl and CuBIm-Br to a gyroidal metal-organic framework (MOF) STU-3 which is composed of Cu ions and Bim ligands are observed through a gas-solid reaction, where the gas is methylamine.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 53
- Issue :
- 96
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 29159362
- Full Text :
- https://doi.org/10.1039/c7cc07510c