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Silver(I)-Catalyzed Widely Applicable Aerobic 1,2-Diol Oxidative Cleavage.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2018 Mar 01; Vol. 57 (10), pp. 2616-2620. Date of Electronic Publication: 2018 Feb 08. - Publication Year :
- 2018
-
Abstract
- The oxidative cleavage of 1,2-diols is a fundamental organic transformation. The stoichiometric oxidants that are still predominantly used for such oxidative cleavage, such as H <subscript>5</subscript> IO <subscript>6</subscript> , Pb(OAc) <subscript>4</subscript> , and KMnO <subscript>4</subscript> , generate stoichiometric hazardous waste. Herein, we describe a widely applicable and highly selective silver(I)-catalyzed oxidative cleavage of 1,2-diols that consumes atmospheric oxygen as the sole oxidant, thus serving as a potentially greener alternative to the classical transformations.<br /> (© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 57
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 29336100
- Full Text :
- https://doi.org/10.1002/anie.201711531