Homoallyl-Substituted Vinylcyclopropanes from α,β-Unsaturated Ketones and Allylindium Derivatives.

Authors :: Höppe HA
Lloyd-Jones GC
Murray M
Peakman TM
Walsh KE
Source :: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 1998 Jun 19; Vol. 37 (11), pp. 1545-1547.
Publication Year :: 1998
Abstract: Simply reversing the order of addition of aqueous acid and Et <subscript>2</subscript> O to the Barbier intermediate 1 of the known indium-mediated allylation leads to unprecedented deoxygenative rearrangements [Eq. (a)].<br /> (© 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)

Language :: English
ISSN :: 1521-3773
Volume :: 37
Issue :: 11
Database :: MEDLINE
Journal :: Angewandte Chemie (International ed. in English)
Publication Type :: Academic Journal
Accession number :: 29710937
Full Text :: https://doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1545::AID-ANIE1545>3.0.CO;2-3

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