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Ce 16 Si 15 O 6 N 32 -An Oxonitridosilicate with Silicon Octahedrally Coordinated by Nitrogen.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 1999 Feb 01; Vol. 38 (3), pp. 357-359. - Publication Year :
- 1999
-
Abstract
- A rarity in solid-state chemistry is octahedrally coordinated silicon. Ce <subscript>16</subscript> Si <subscript>15</subscript> O <subscript>6</subscript> N <subscript>32</subscript> is the first nitridosilicate with this structural motif. Most oxosilicates containing octahedrally coordinated silicon are high-pressure phases. In contrast to that Ce <subscript>16</subscript> Si <subscript>15</subscript> O <subscript>6</subscript> N <subscript>32</subscript> has been synthesized under ambient pressure. An SiN <subscript>6</subscript> octahedron that is surrounded by two parallel rings formed from six Si(O,N) <subscript>4</subscript> tetrahedra is depicted.<br /> (© 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 38
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 29711659
- Full Text :
- https://doi.org/10.1002/(SICI)1521-3773(19990201)38:3<357::AID-ANIE357>3.0.CO;2-D