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Counter-Rotating Ring Currents in Coronene and Corannulene.

Authors :
Steiner E
Fowler PW
Jenneskens LW
Source :
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2001 Jan 19; Vol. 40 (2), pp. 362-366.
Publication Year :
2001

Abstract

Explicit ab initio current-density maps contradict the annulene-within-an-annulene model of [n]circulenes: in both coronene and corannulene the expected diamagnetic current on the perimeter is opposed by the central, paramagnetic ring current.<br /> (© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.)

Details

Language :
English
ISSN :
1521-3773
Volume :
40
Issue :
2
Database :
MEDLINE
Journal :
Angewandte Chemie (International ed. in English)
Publication Type :
Academic Journal
Accession number :
29712401
Full Text :
https://doi.org/10.1002/1521-3773(20010119)40:2<362::AID-ANIE362>3.0.CO;2-Z