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Photochemical reductive homologation of hydrogen cyanide using sulfite and ferrocyanide.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 May 29; Vol. 54 (44), pp. 5566-5569. - Publication Year :
- 2018
-
Abstract
- Photoredox cycling during UV irradiation of ferrocyanide ([FeII(CN)6]4-) in the presence of stoichiometric sulfite (SO32-) is shown to be an extremely effective way to drive the reductive homologation of hydrogen cyanide (HCN) to simple sugars and precursors of hydroxy acids and amino acids.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 54
- Issue :
- 44
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 29761807
- Full Text :
- https://doi.org/10.1039/c8cc01499j