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Single-molecule magnet properties of a monometallic dysprosium pentalene complex.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2018 Jun 21; Vol. 54 (51), pp. 7085-7088. - Publication Year :
- 2018
-
Abstract
- The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2- ligand.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 54
- Issue :
- 51
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 29878012
- Full Text :
- https://doi.org/10.1039/c8cc03516d