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Vanadium-Catalyzed Dehydrogenation of N-Heterocycles in Water.

Authors :
Zumbrägel N
Sako M
Takizawa S
Sasai H
Gröger H
Source :
Organic letters [Org Lett] 2018 Aug 17; Vol. 20 (16), pp. 4723-4727. Date of Electronic Publication: 2018 Aug 01.
Publication Year :
2018

Abstract

In this paper, the dehydrogenation of tetrahydroquinolines using oxovanadium(V) catalysts under mild conditions in water and oxygen atmosphere is described. This catalytic technology was successfully applied to a range of other structurally related N-heterocycles, and a reaction mechanism is proposed.

Details

Language :
English
ISSN :
1523-7052
Volume :
20
Issue :
16
Database :
MEDLINE
Journal :
Organic letters
Publication Type :
Academic Journal
Accession number :
30067034
Full Text :
https://doi.org/10.1021/acs.orglett.8b01484