Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework.

Authors :: Godfrey HGW
da Silva I
Briggs L
Carter JH
Morris CG
Savage M
Easun TL
Manuel P
Murray CA
Tang CC
Frogley MD
Cinque G
Yang S
Schröder M
Source :: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2018 Nov 05; Vol. 57 (45), pp. 14778-14781. Date of Electronic Publication: 2018 Oct 01.
Publication Year :: 2018
Abstract: MFM-300(Al) shows reversible uptake of NH <subscript>3</subscript> (15.7 mmol g <superscript>-1</superscript> at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm <superscript>-3</superscript> at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro-spectroscopy on ND <subscript>3</subscript> @MFM-300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.<br /> (© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

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