Nitrogen-Doped Microporous Carbons Derived from Pyridine Ligand-Based Metal-Organic Complexes as High-Performance SO 2 Adsorption Sorbents.

Heteroatom-doped porous carbons are emerging as platforms for gas adsorption. Herein, N-doped microporous carbon (NPC) materials have been synthesized by carbonization of two pyridine ligand-based metal-organic complexes (MOCs) at high temperatures (800, 900, 1000, and 1100 °C). For NPCs (termed NPC-1- T and NPC-2- T, where T represents the carbonization temperature), the micropore is dominant, pyridinic-N and other N atoms of MOC precursors are mostly retained, and the N content reaches as high as 16.61%. They all show high Brunauer-Emmett-Teller surface area and pore volume, in particular, NPC-1-900 exhibits the highest surface areas and pore volumes, up to 1656.2 m ² g ^-1 and 1.29 cm ³ g ^-1 , respectively, a high content of pyridinic-N (7.3%), and a considerable amount of SO ₂ capture (118.1 mg g ^-1 ). Theoretical calculation (int = ultrafine m062x) indicates that pyridinic-N acts as the leading active sites contributing to high SO ₂ adsorption and that the higher content of pyridinic-N doping into the graphite carbon layer structure could change the electrostatic surface potential, as well as the local electronic density, which enhanced SO ₂ absorption on carbon edge positions. The results show great potential for the preparation of microporous carbon materials from pyridine ligand-based MOCs for effective SO ₂ adsorption.