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Lithium- and Magnesium-Storage Mechanisms of Novel Hexagonal NbSe 2 .
- Source :
-
ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2018 Oct 31; Vol. 10 (43), pp. 36988-36995. Date of Electronic Publication: 2018 Oct 18. - Publication Year :
- 2018
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Abstract
- As a novel and potential transition metal dichalcogenide (TMDC), NbSe <subscript>2</subscript> has low ion diffusion barrier when applied in energy-storage systems, such as traditional lithium-ion batteries and novel magnesium-ion batteries (MIBs). In this work, we have developed a novel hexagonal NbSe <subscript>2</subscript> material with a nanosized surface via a facile microwave-hydrothermal method. The Li <superscript>+</superscript> -storage mechanism of NbSe <subscript>2</subscript> with surface conversion and internal intercalation is thoroughly revealed by in situ X-ray diffraction (XRD), ex situ high-resolution transmission electron microscopy, and ex situ scanning electron microscopy. Besides, Mg <superscript>2+</superscript> intercalation mechanism is confirmed via ex situ XRD and ex situ X-ray photoelectron spectroscopy for the first time. In addition, as the cathode for MIBs, NbSe <subscript>2</subscript> with a nanosized surface exhibits a high rate capacity of 101 mA h g <superscript>-1</superscript> at 200 mA g <superscript>-1</superscript> with a high discharge plateau at 1.30 V. Our work builds a deep understanding of ion-storage mechanisms in TMDCs and provides guidance for designing new electrode materials with high electrochemical performances.
Details
- Language :
- English
- ISSN :
- 1944-8252
- Volume :
- 10
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- ACS applied materials & interfaces
- Publication Type :
- Academic Journal
- Accession number :
- 30299077
- Full Text :
- https://doi.org/10.1021/acsami.8b12662