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Transition-Metal-Free Desulfinative Cross-Coupling of Heteroaryl Sulfinates with Grignard Reagents.
- Source :
-
Organic letters [Org Lett] 2019 Feb 15; Vol. 21 (4), pp. 937-940. Date of Electronic Publication: 2019 Jan 24. - Publication Year :
- 2019
-
Abstract
- A mild cross-coupling reaction of heteroaryl sulfinates with Grignard reagents has been developed under transition-metal-free conditions. This study provides an example of the SO <subscript>2</subscript> <superscript>2-</superscript> as a leaving group in an aromatic system and an effective methodology for the construction of C-C bond.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 21
- Issue :
- 4
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 30676757
- Full Text :
- https://doi.org/10.1021/acs.orglett.8b03918