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Redox chemistry of an anionic dithiolene radical.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2019 Mar 12; Vol. 48 (11), pp. 3543-3546. - Publication Year :
- 2019
-
Abstract
- The redox chemistry of the first stable anionic dithiolene radical 1˙ was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of 1˙ by Cp2Co or KC8 affords the corresponding dithiolate dimers 2 and 3, respectively, one-electron oxidation of 1˙ by Ph3C+BF4- (or O2) conveniently gives 4, the neutral dithiolene dimer.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 48
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 30747182
- Full Text :
- https://doi.org/10.1039/c8dt04989k