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Cyclization of Terphenyl-Bisfluorenols: A Mechanistic Study of the Regioselectvity.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2019 Aug 09; Vol. 25 (45), pp. 10689-10697. Date of Electronic Publication: 2019 Jul 15. - Publication Year :
- 2019
-
Abstract
- The mechanism of the bicyclization reaction of a series of terphenyl-bisfluorenols into dispiro[fluorene-9,6'-indeno[1,2-b]fluorene-12',9''-fluorene] and dispiro[fluorene-9,6'-indeno[2,1-a]fluorene-12',9''-fluorene] is reported. Through a combined experimental and theoretical study, the different parameters that drive the regioselectivity of this cyclization reaction have been studied and are presented.<br /> (© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 25
- Issue :
- 45
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 31087579
- Full Text :
- https://doi.org/10.1002/chem.201901457