Nitrofurantoin in sediments and soils: Sorption, isotherms and kinetics.

Nitrofurantoin is nitrofuran antibacterial drug that is most used as a veterinary pharmaceutic compound. This compound, as well as other pharmaceuticals can greatly affect the environment, the soil and organisms in it and pollute aquatic ecosystems. Since it has been used for only a few decades, knowledge of their fate and behaviour in the environment is still limited. Because of that, the aim of this study was to experimentally determine the K _d values of nitrofurantoin in seven different natural soil and seven different sediment samples with different physico-chemical properties. Sorption phenomena were described with Linear, Freundlich and Dubinin-Radushkevich sorption isotherms. Obtained sorption coefficients (K _d ) ranged from 3.967 to 5.121 mLg ^-1 for sediment samples and 3.634-43.06 mL g ^-1 for soil samples. The influence of ionic strength and pH of the nitrofurantoin solution and kinetics of the sorption and desorption process were also investigated. Results show that an increase in ionic strength and pH reduces the values of sorption coefficient while the mechanism of nitrofurantoin sorption is the best described with the kinetic model of pseudo-second order.
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