Efficient Gas Adsorption Using Superamphiphobic Porous Monoliths as the under-Liquid Gas-Conductive Circuits.

The gas-liquid membrane contactor forms a gas-solid-liquid interface and has a high potential for the applications in gas adsorption, catalysis, energy exchange, and so on. Porous superhydrophobic membranes show a great gas separation/adsorption ability. However, the complicated device architecture and the durability issue are normally concerned especially for the continuous circulation of gas and liquid. In this work, we present a free-standing gas-conductive circuit simply formed by connecting the superamphiphobic porous monoliths (SAPMs) to achieve an efficient under-liquid gas adsorption. The porous worm-like SAPM is prepared with low-temperature expandable graphite and polyvinylidenefluoride, exhibiting superamphiphobicity and superaerophilicity after fluoridation. The as-made SAPM circuits can be used as a reliable gas conductor under numerous liquids, such as water, alkaline, acidic, and oily solutions. In this work, the CO ₂ adsorption capacities of the SAPM circuits are evaluated under NaOH and methyldiethanolamine solutions and the mass transfer rate can reach up to 9.61 mmol m ^-2 s ^-1 . Moreover, the effective human blood oxygenation process is also demonstrated using SAPM circuits. Thus, the reported SAPM provides an alternative gas-liquid exchanging method and the simplified process could be of great benefit to the cost-effectively large-scale CO ₂ capture or gas exchanging applications.