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Torsional chirality generation based on cyclic oligomers constructed from an odd number of pyrenes.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2019 Aug 21; Vol. 55 (65), pp. 9618-9621. Date of Electronic Publication: 2019 Jul 18. - Publication Year :
- 2019
-
Abstract
- A Ni(0)-mediated coupling reaction of a 1,8-dibromopyrene gave a series of cyclic pyrene oligomers CPn up to nonadecamer. CP5 and CP7 represent a unique class of asymmetric compounds with no stereogenic chiral centers in terms of their global chirality, which are achieved because of an odd number of pyrenes.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 55
- Issue :
- 65
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 31318367
- Full Text :
- https://doi.org/10.1039/c9cc03123e