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Homogeneous Core/Shell NiMoO 4 @NiMoO 4 and Activated Carbon for High Performance Asymmetric Supercapacitor.

Authors :
Dong JY
Xu JC
Hui KN
Yang Y
Su SC
Li L
Zhang XT
Ng KW
Wang SP
Tang ZK
Source :
Nanomaterials (Basel, Switzerland) [Nanomaterials (Basel)] 2019 Jul 19; Vol. 9 (7). Date of Electronic Publication: 2019 Jul 19.
Publication Year :
2019

Abstract

Here, we report the extraordinary electrochemical energy storage capability of NiMoO <subscript>4</subscript> @NiMoO <subscript>4</subscript> homogeneous hierarchical nanosheet-on-nanowire arrays (SOWAs), synthesized on nickel substrate by a two-stage hydrothermal process. Comparatively speaking, the SOWAs electrode displays superior electrochemical performances over the pure NiMoO <subscript>4</subscript> nanowire arrays. Such improvements can be ascribed to the characteristic homogeneous hierarchical structure, which not only effectively increases the active surface areas for fast charge transfer, but also reduces the electrode resistance significantly by eliminating the potential barrier at the nanowire/nanosheet junction, an issue usually seen in other reported heterogeneous architectures. We further evaluate the performances of the SOWAs by constructing an asymmetric hybrid supercapacitor (ASC) with the SOWAs and activated carbon (AC). The optimized ASC shows excellent electrochemical performances with 47.2 Wh/kg in energy density of 1.38 kW/kg at 0-1.2 V. Moreover, the specific capacity retention can be as high as 91.4% after 4000 cycles, illustrating the remarkable cycling stability of the NiMoO <subscript>4</subscript> @NiMoO <subscript>4</subscript> //AC ASC device. Our results show that this unique NiMoO <subscript>4</subscript> @NiMoO <subscript>4</subscript> SOWA has great prospects for future energy storage applications.

Details

Language :
English
ISSN :
2079-4991
Volume :
9
Issue :
7
Database :
MEDLINE
Journal :
Nanomaterials (Basel, Switzerland)
Publication Type :
Academic Journal
Accession number :
31331029
Full Text :
https://doi.org/10.3390/nano9071033