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Rotational spectroscopy of organophosphorous chemical agents: cresyl and phenyl saligenin phosphates.

Authors :
Saragi RT
Juanes M
Abad JL
Lesarri A
Pinacho R
Rubio JE
Source :
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2019 Aug 14; Vol. 21 (30), pp. 16418-16422. Date of Electronic Publication: 2019 Jul 23.
Publication Year :
2019

Abstract

Cresyl and phenyl saligenin phosphates have been probed in a jet expansion by broadband chirp-excitation microwave spectroscopy, revealing the most stable conformations and their structural properties. The rotational parameters offer a high-resolution univocal route for characterization of organophosphorous agents and a testbed for computational models.

Details

Language :
English
ISSN :
1463-9084
Volume :
21
Issue :
30
Database :
MEDLINE
Journal :
Physical chemistry chemical physics : PCCP
Publication Type :
Academic Journal
Accession number :
31332416
Full Text :
https://doi.org/10.1039/c9cp03093j