Prediction of soil available water-holding capacity from visible near-infrared reflectance spectra.

Sustainable land management requires reliable information about soil hydraulic properties. Among these properties, available water-holding capacity (AWC) is a key attribute, as it quantifies the amount of water available for plants that the soil can hold. Since direct measurements of AWC are costly, pedotransfer functions (PTF) are often used to estimate AWC, leveraging statistical relationships with properties that are easier to measure, such as texture, bulk density, and organic carbon content. This study evaluates visible near-infrared spectroscopy (vis-NIR) as an alternative approach to predict volumetric water content at field capacity (FC) and permanent wilting point (PWP) - AWC being the difference between PWP and FC. A suite of 970 vis-NIR soil spectra, recorded from air-dried, 2-mm, sieved soil samples, were associated with FC and PWP analytical data obtained from New Zealand's National Soils Database. Partial least squares (PLS) regression and support vector machines on PLS latent variables (PLS-SVM) were used for spectroscopic modelling. With root mean squared errors below 7% and 5% for FC and PWP, respectively, our results indicate that vis-NIR spectroscopy can be used to quantitatively predict volumetric water content at FC and PWP.