Crystal structure of poly[[di-aqua-tetra-μ 2 -cyanido-iron(II)platinum(II)] acetone disolvate].

Authors :: Kuzevanova IS
Naumova DD
Terebilenko KV
Shova S
Gural'skiy IA
Source :: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2019 Sep 27; Vol. 75 (Pt 10), pp. 1536-1539. Date of Electronic Publication: 2019 Sep 27 (Print Publication: 2019).
Publication Year :: 2019
Abstract: In the title polymeric complex, {[FePt(CN) <subscript>4</subscript> (H <subscript>2</subscript> O) <subscript>2</subscript> ]·2C <subscript>3</subscript> H <subscript>6</subscript> O} <subscript> n </subscript> , the Fe <superscript>II</superscript> cation has an octa-hedral [FeN <subscript>4</subscript> O <subscript>2</subscript> ] geometry being coordinated by two water mol-ecules and four cyanide anions. The Pt cation is located on an inversion centre and has a square-planar coordination environment formed by four cyanide groups. The tetra-cyano-platinate anions bridge the Fe <superscript>II</superscript> cations to form infinite two-dimensional layers that propagate in the bc plane. Two guest mol-ecules of acetone per Fe <superscript>II</superscript> are located between the layers. These guest acetone mol-ecules inter-act with the coordinated water mol-ecules by O-H⋯O hydrogen bonds.<br /> (© Kuzevanova et al. 2019.)

Language :: English
ISSN :: 2056-9890
Volume :: 75
Issue :: Pt 10
Database :: MEDLINE
Journal :: Acta crystallographica. Section E, Crystallographic communications
Publication Type :: Academic Journal
Accession number :: 31636989
Full Text :: https://doi.org/10.1107/S2056989019012945

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