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Planar B 41 - and B 42 - clusters with double-hexagonal vacancies.

Authors :
Bai H
Chen TT
Chen Q
Zhao XY
Zhang YY
Chen WJ
Li WL
Cheung LF
Bai B
Cavanagh J
Huang W
Li SD
Li J
Wang LS
Source :
Nanoscale [Nanoscale] 2019 Dec 28; Vol. 11 (48), pp. 23286-23295. Date of Electronic Publication: 2019 Nov 29.
Publication Year :
2019

Abstract

Since the discovery of the B <subscript>40</subscript> borospherene, research interests have been directed to the structural evolution of even larger boron clusters. An interesting question concerns if the borospherene cages persist in larger boron clusters like the fullerenes. Here we report a photoelectron spectroscopy (PES) and computational study on the structures and bonding of B <subscript>41</subscript> <superscript>-</superscript> and B <subscript>42</subscript> <superscript>-</superscript> , the largest boron clusters characterized experimentally thus far. The PE spectra of both clusters display broad and complicated features, suggesting the existence of multiple low-lying isomers. Global minimum searches for B <subscript>41</subscript> <superscript>-</superscript> reveal three low-lying isomers (I-III), which are all related to the planar B <subscript>40</subscript> <superscript>-</superscript> structure. Isomer II (C <subscript>s</subscript> , <superscript>1</superscript> A') possessing a double hexagonal vacancy is found to agree well with the experiment, while isomers I (C <subscript>s</subscript> , <superscript>3</superscript> A'') and III (C <subscript>s</subscript> , <superscript>1</superscript> A') both with a single hexagonal vacancy are also present as minor isomers in the experiment. The potential landscape of B <subscript>42</subscript> <superscript>-</superscript> is found to be much more complicated with numerous low-lying isomers (VII-XII). The quasi-planar structure VIII (C <subscript>1</subscript> , <superscript>2</superscript> A) containing a double hexagonal vacancy is found to make major contributions to the observed PE spectrum of B <subscript>42</subscript> <superscript>-</superscript> , while the other low-lying isomers may also be present to give rise to a complicated spectral pattern. Chemical bonding analyses show isomer II of B <subscript>41</subscript> <superscript>-</superscript> (C <subscript>s</subscript> , <superscript>1</superscript> A') and isomer VIII of B <subscript>42</subscript> <superscript>-</superscript> (C <subscript>1</subscript> , <superscript>2</superscript> A) are π aromatic, analogous to that in the polycyclic aromatic hydrocarbon C <subscript>27</subscript> H <subscript>13</subscript> <superscript>+</superscript> (C <subscript>2v</subscript> , <superscript>1</superscript> A <subscript>1</subscript> ). Borospherene cage isomers are also found for both B <subscript>41</subscript> <superscript>-</superscript> and B <subscript>42</subscript> <superscript>-</superscript> in the global minimum searches, but they are much higher energy isomers.

Details

Language :
English
ISSN :
2040-3372
Volume :
11
Issue :
48
Database :
MEDLINE
Journal :
Nanoscale
Publication Type :
Academic Journal
Accession number :
31782482
Full Text :
https://doi.org/10.1039/c9nr09522e