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Enzymatic Synthesis of Methylated Terpene Analogues Using the Plasticity of Bacterial Terpene Synthases.
- Source :
-
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2020 Feb 17; Vol. 26 (10), pp. 2178-2182. Date of Electronic Publication: 2020 Jan 30. - Publication Year :
- 2020
-
Abstract
- Methylated analogues of isopentenyl diphosphate were synthesised and enzymatically incorporated into methylated terpenes. A detailed stereochemical analysis of the obtained products is presented. The methylated terpene precursors were also used in conjunction with various isotopic labellings to gain insights into the mechanisms of their enzymatic formation.<br /> (© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.)
- Subjects :
- Chloroflexi enzymology
Chryseobacterium enzymology
Hemiterpenes chemical synthesis
Hemiterpenes chemistry
Hemiterpenes metabolism
Methylation
Organophosphorus Compounds chemical synthesis
Organophosphorus Compounds chemistry
Organophosphorus Compounds metabolism
Stereoisomerism
Terpenes chemistry
Alkyl and Aryl Transferases metabolism
Bacteria enzymology
Bacterial Proteins metabolism
Terpenes metabolism
Subjects
Details
- Language :
- English
- ISSN :
- 1521-3765
- Volume :
- 26
- Issue :
- 10
- Database :
- MEDLINE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 31898827
- Full Text :
- https://doi.org/10.1002/chem.201905827