Highly Reversible Cuprous Mediated Cathode Chemistry for Magnesium Batteries.

Sluggish kinetics and poor reversibility of cathode chemistry is the major challenge for magnesium batteries to achieve high volumetric capacity. Introduction of the cuprous ion (Cu ⁺ ) as a charge carrier can decouple the magnesiation related energy storage from the cathode electrochemistry. Cu ⁺ is generated from a fast equilibrium between copper selenide electrode and Mg electrolyte during standing time, rather than in the electrochemical process. A reversible chemical magnesiation/de-magnesiation can be driven by this solid/liquid equilibrium. During a typical discharge process, Cu ⁺ is reduced to Cu and drives the equilibrium to promote the magnesiation process. The reversible Cu to Cu ⁺ redox promotes the recharge process. This novel Cu ⁺ mediated cathode chemistry of Mg battery leads to a high reversible areal capacity of 12.5 mAh cm ^-2 with high mass loading (49.1 mg cm ^-2 ) of the electrode. 80 % capacity retention can be achieved for 200 cycles after a conditioning process.
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