Highly Flexible and Patternable Multiwalled-Carbon Nanotube/Nitrocellulose Hybrid Conducting Paper Electrodes as Heating Platforms for Effective Ignition of Nanoenergetic Materials.

In this study, a highly flexible, patternable multiwalled-carbon nanotube (MWCNT) paper electrode was specially designed and fabricated. The addition of a nitrocellulose (NC) polymer binder at less than the critical amount (≤2 wt %) was found to be effective for maintaining both the flexibility and electrical conductance of the resulting MWCNT paper electrode. The fabricated MWCNT paper electrode was then employed as a heating platform to ignite Al/CuO nanoparticle-based nanoenergetic materials (nEMs). The nEM layer was drop-cast on the surface of the MWCNT paper electrode with specially patterned shapes using a plotter, and its ignition was evaluated by applying various voltages through the MWCNT paper electrode. To increase the adhesion between the nEM layer and MWCNT paper electrode and to decrease the sparking sensitivity of the nEM layer, it was essential to incorporate NC in the nEM matrix. However, the combustion and explosion properties of nEM layers deteriorated with the addition of NC, enabling the estimation of the optimum amount of NC to be incorporated. The fabricated igniter can be employed in various thermal engineering applications, such as in the ignition of explosives and propellants, and in pyrotechnics. To demonstrate this, a compact, flexible, and patternable igniter composed of the NC/nEM layer (NC/nEM = 2:8 wt %) on an MWCNT paper electrode was used to successfully ignite solid propellants for launching a small rocket.