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Synthesis of Ar@C 60 using molecular surgery.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Sep 10; Vol. 56 (72), pp. 10521-10524. - Publication Year :
- 2020
-
Abstract
- Synthesis of Ar@C60 is described, using a route in which high-pressure argon filling of an open-fullerene and photochemical desulfinylation are the key steps for >95% encapsulation of the noble gas. Enrichment by recycling HPLC leads to quantitative incorporation of argon in the product endofullerene, with a mass recovery of tens of milligrams, allowing the first characterisation of fine structure in the solution 13C NMR spectrum.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 56
- Issue :
- 72
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 32779650
- Full Text :
- https://doi.org/10.1039/d0cc04201c