Determination of in a sequential injection lab-on-valve system with voltammetric detection using a modified electrode.

A stripping voltammetric assay using a morin modified electrode in a sequential injection lab-on-valve system was developed for the determination of trace amounts of cadmium. The sample and reagent arrangements were achieved by a syringe pump. The target metal ions were accumulated on the morin modified glassy carbon electrode surface, and the quantification step was performed by subsequent anodic stripping voltammetry. The key experimental variables relevant to the voltammetric measurement procedure were optimized. For a 100 s preconcentration time, a linear calibration curve was obtained for a concentration range of 1 to 125 μg L-1 with a detection limit of 0.41 μg L-1. The analytical use of the established method was assessed by applying it to the determination of cadmium in real samples and carrying out recovery experiments. The method was subsequently validated by comparing the results with those given by ICP-OES.