Back to Search
Start Over
On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A-C.
- Source :
-
Beilstein journal of organic chemistry [Beilstein J Org Chem] 2020 Nov 19; Vol. 16, pp. 2807-2819. Date of Electronic Publication: 2020 Nov 19 (Print Publication: 2020). - Publication Year :
- 2020
-
Abstract
- A <superscript>13</superscript> C-labelling was introduced into each individual carbon of the recently discovered sestermobaraenes by the enzymatic conversion of the correspondingly <superscript>13</superscript> C-labelled isoprenyl diphosphate precursors with the sestermobaraene synthase from Streptomyces mobaraensis . The main compounds sestermobaraenes A, B, and C were analysed by gas chromatography-mass spectrometry (GC-MS), allowing for a deep mechanistic investigation of the electron impact mass spectrometry (EIMS) fragmentation reactions of these sesterterpene hydrocarbons.<br /> (Copyright © 2020, Hou and Dickschat; licensee Beilstein-Institut.)
Details
- Language :
- English
- ISSN :
- 1860-5397
- Volume :
- 16
- Database :
- MEDLINE
- Journal :
- Beilstein journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 33281984
- Full Text :
- https://doi.org/10.3762/bjoc.16.231