Role of iodine oxoacids in atmospheric aerosol nucleation.

Iodic acid (HIO ₃ ) is known to form aerosol particles in coastal marine regions, but predicted nucleation and growth rates are lacking. Using the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber, we find that the nucleation rates of HIO ₃ particles are rapid, even exceeding sulfuric acid-ammonia rates under similar conditions. We also find that ion-induced nucleation involves IO ₃ ^- and the sequential addition of HIO ₃ and that it proceeds at the kinetic limit below +10°C. In contrast, neutral nucleation involves the repeated sequential addition of iodous acid (HIO ₂ ) followed by HIO ₃ , showing that HIO ₂ plays a key stabilizing role. Freshly formed particles are composed almost entirely of HIO ₃ , which drives rapid particle growth at the kinetic limit. Our measurements indicate that iodine oxoacid particle formation can compete with sulfuric acid in pristine regions of the atmosphere.
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