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Polymerization via Insertion of Ethylene into Al-C bond under Mild Conditions: Mechanistic Studies on the Promotion Exerted by a Catalytic Amount of Cationic Gadolinium Metallocene.
- Source :
-
Chemistry, an Asian journal [Chem Asian J] 2021 Jun 01; Vol. 16 (11), pp. 1403-1416. Date of Electronic Publication: 2021 Apr 30. - Publication Year :
- 2021
-
Abstract
- The cationic gadolinium metallocene [(C <subscript>5</subscript> Me <subscript>5</subscript> ) <subscript>2</subscript> Gd][B(C <subscript>6</subscript> F <subscript>5</subscript> ) <subscript>4</subscript> ], when combined with an excess amount of Al( <superscript>i</superscript> Bu) <subscript>3</subscript> , efficiently produces polyethylene at 80 °C under 0.8 MPa pressure of ethylene. After quenching, the resulting polyethylene has ethyl group at one end and isobutyl group at the other terminal. Because no Gd-alkyl species appears to be involved, a mechanism with conventional coordinative chain transfer polymerization (CCTP) is not feasible. Density functional theory (DFT) analyses indicate a novel mechanism in which the cationic Gd plays a crucial role by coordinating ethylene and assists the insertion of the coordinated ethylene into Al-C bond.<br /> (© 2021 Wiley-VCH GmbH.)
Details
- Language :
- English
- ISSN :
- 1861-471X
- Volume :
- 16
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Chemistry, an Asian journal
- Publication Type :
- Academic Journal
- Accession number :
- 33792197
- Full Text :
- https://doi.org/10.1002/asia.202100193