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Rapid 18 F-labeling via Pd-catalyzed S-arylation in aqueous medium.

Authors :
Humpert S
Omrane MA
Urusova EA
Gremer L
Willbold D
Endepols H
Krasikova RN
Neumaier B
Zlatopolskiy BD
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Apr 14; Vol. 57 (29), pp. 3547-3550. Date of Electronic Publication: 2021 Mar 19.
Publication Year :
2021

Abstract

We report radiolabeling of thiol-containing substrates via Pd-catalyzed S-arylation with 2-[ <superscript>18</superscript> F]fluoro-5-iodopyridine, which is readily accessible using the "minimalist" radiofluorination method. The practicality of the procedure was confirmed by preparation of a novel PSMA-specific PET-tracer as well as labeling of glutathione, Aβ oligomer-binding RD2 peptide, bovine serum albumin and PSMA I&S.

Details

Language :
English
ISSN :
1364-548X
Volume :
57
Issue :
29
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
33870341
Full Text :
https://doi.org/10.1039/d1cc00745a