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Sustainable preparation of cellulose nanofibrils via choline chloride-citric acid deep eutectic solvent pretreatment combined with high-pressure homogenization.
- Source :
-
Carbohydrate polymers [Carbohydr Polym] 2021 Sep 01; Vol. 267, pp. 118220. Date of Electronic Publication: 2021 May 21. - Publication Year :
- 2021
-
Abstract
- Developing green and simple methods for the preparation of cellulose nanofibrils (CNFs) is of great significance. Herein, a green deep eutectic solvent (DES) system based on choline chloride (ChCl) and citric acid (CA) is employed to pretreat cellulose fibers for the preparation of CNFs. The effect of the pretreatment temperature on the chemo-physical properties of the CNFs is comprehensively investigated. A high CNFs yield of up to 84.19% can be achieved under optimized conditions. The optimal CNFs show a narrow diameter distribution and length up to several microns, high crystallinity and thermal stability, as well as excellent dispersibility in water. Furthermore, semi-transparent and flexible cellulose nanopaper (CNP) was fabricated through a facile vacuum filtration process. The optimal CNP shows high tensile strength (175.15 MPa) and toughness (7.51 MJ/m <superscript>3</superscript> ). Therefore, this work provides a sustainable and facile approach to fabricate CNFs and CNP, which can be potentially used for various high-tech applications.<br /> (Copyright © 2021. Published by Elsevier Ltd.)
Details
- Language :
- English
- ISSN :
- 1879-1344
- Volume :
- 267
- Database :
- MEDLINE
- Journal :
- Carbohydrate polymers
- Publication Type :
- Academic Journal
- Accession number :
- 34119174
- Full Text :
- https://doi.org/10.1016/j.carbpol.2021.118220