Room-temperature spin nutations in a magnetically condensed phase of [Y(pc) 2 ]˙.

Authors :: Boudalis AK
Olivares-Peña JE
Moreno-Pineda E
Fediai A
Wenzel W
Turek P
Ruben M
Source :: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Nov 02; Vol. 57 (87), pp. 11505-11508. Date of Electronic Publication: 2021 Nov 02.
Publication Year :: 2021
Abstract: FID-detected nutations of the antiferromagnetic crystal form of [Y(pc) <subscript>2</subscript> ]˙ demonstrated that its radical spin can be coherently driven in its magnetically condensed undeuterated phase and at room temperature. Liquid-helium nutations revealed additional Rabi oscillations assigned to transitions within higher-multiplicity states of finite-sized chain fragments.

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