Solution-Processed, Inverted AgBiS 2 Nanocrystal Solar Cells.

AgBiS ₂ nanocrystals are a promising nontoxic alternative to PbS, CsPbI ₃ , and CdS quantum dots for solution-fabricated nanocrystal photovoltaics. In this work, we fabricated the first inverted (p-i-n) structure AgBiS ₂ nanocrystal solar cells. We selected spray-coated NiO as the hole-transporting material and used PCBM/BCP as the electron-transporting material. Combining transient photocurrent and photovoltage measurements with femtosecond transient absorption spectroscopy, we investigated the charge collection process on metal oxide/AgBiS ₂ interfaces and demonstrated that the NiO/AgBiS ₂ NC junction in the p-i-n configuration is more efficient for charge carrier collection. The fabricated p-i-n solar cells exhibited a 4.3% power conversion efficiency (PCE), which was higher than that of conventional n-i-p solar cells fabricated using the same sample. Additionally, inverted devices showed an ultrahigh short-circuit current ( J _SC ) over 20.7 mA cm ^-2 and 0.38 V open-circuit voltage ( V _OC ), suggesting their potential for further improvements in efficiency and, eventually, for large-scale production.