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Acid-Free Copper-Catalyzed Electrophilic Nitration of Electron-Rich Arenes with Guanidine Nitrate.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2022 Mar 04; Vol. 87 (5), pp. 3834-3840. Date of Electronic Publication: 2022 Feb 16. - Publication Year :
- 2022
-
Abstract
- A practical copper-catalyzed nitration of electron-rich arenes with trimethylsilyl chloride and guanidine nitrate is reported. A variety of nitrated products were generated in moderate to excellent yields (32-99%) at ambient temperature under acid-free, open-flask, and operationally simple conditions.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 87
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 35168320
- Full Text :
- https://doi.org/10.1021/acs.joc.1c03020