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Deceptive Complexity in Formation of Cleistantha-8,12-diene.
- Source :
-
Organic letters [Org Lett] 2022 Apr 15; Vol. 24 (14), pp. 2646-2649. Date of Electronic Publication: 2022 Apr 06. - Publication Year :
- 2022
-
Abstract
- A barley diterpene synthase (HvKSL4) was found to produce (14 S )-cleistantha-8,12-diene ( 1 ). Formation of the nearly planar cyclohexa-1,4-diene configuration leaves the ring poised for aromatization, but necessitates a deceptively complicated series of rearrangements steered through a complex energetic landscape, as elucidated here through quantum chemical calculations and labeling studies.
- Subjects :
- Plant Leaves
Diterpenes
Subjects
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 24
- Issue :
- 14
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 35385666
- Full Text :
- https://doi.org/10.1021/acs.orglett.2c00680