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NaV 6 O 15 microflowers as a stable cathode material for high-performance aqueous zinc-ion batteries.

Authors :
Li R
Guan C
Bian X
Yu X
Hu F
Source :
RSC advances [RSC Adv] 2020 Feb 13; Vol. 10 (12), pp. 6807-6813. Date of Electronic Publication: 2020 Feb 13 (Print Publication: 2020).
Publication Year :
2020

Abstract

Reversible aqueous zinc-ion batteries (ZIBs) have great potential for large-scale energy storage owing to their low cost and safety. However, the lack of long-lifetime positive materials severely restricts the development of ZIBs. Herein, we report NaV <subscript>6</subscript> O <subscript>15</subscript> microflowers as a cathode material for ZIBs with excellent electrochemical performance, including a high specific capacity of ∼300 mA h g <superscript>-1</superscript> at 100 mA g <superscript>-1</superscript> and 141 mA h g <superscript>-1</superscript> maintained after 2000 cycles at 5 A g <superscript>-1</superscript> with a capacity retention of ∼107%. The high diffusion coefficient and stable tunneled structure of NaV <subscript>6</subscript> O <subscript>15</subscript> facilitate Zn <superscript>2+</superscript> intercalation/extraction and long-term cycle stability.<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © The Royal Society of Chemistry.)

Details

Language :
English
ISSN :
2046-2069
Volume :
10
Issue :
12
Database :
MEDLINE
Journal :
RSC advances
Publication Type :
Academic Journal
Accession number :
35493911
Full Text :
https://doi.org/10.1039/d0ra00365d