Modification of Talc@TiO 2 toward high-performance nitrile rubber application.

Authors :: He C
Zhang L
Chen D
Fan X
Cai Z
Zhu M
Source :: RSC advances [RSC Adv] 2018 May 11; Vol. 8 (31), pp. 17300-17311. Date of Electronic Publication: 2018 May 11 (Print Publication: 2018).
Publication Year :: 2018
Abstract: To improve the dispersion of talcum powder (Talc) for polymer applications, modified nano-titania powders (TiO <subscript>2</subscript> ) using a silane coupling agent (KH550), a titanate coupling agent (NDZ201) and sodium polyacrylate (PAAS) were well adhered to the surface of Talc with a ball milling method, thereby preparing a series of mixed Talc@TiO <subscript>2</subscript> particles to realize good dispersion in carboxylated acrylonitrile-butadiene rubber (XNBR). Note that Talc@TiO <subscript>2</subscript> particles modified by PAAS and NDZ201 show better colloidal dispersion in anhydrous ethanol due to organification and repulsion of charge, with original Talc and NDZ201 modified Talc@TiO <subscript>2</subscript> powders as a comparison. Modified Talc@TiO <subscript>2</subscript> hybrid XNBR shows good performance characteristics, including damping capacity and impact resistance, depending mainly on the excellent mechanical property of Talc, good dispersion and the high adhesive force between modified Talc@TiO <subscript>2</subscript> and XNBR.<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © The Royal Society of Chemistry.)