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Poly( para -arylene)s via [2+2+2].

Authors :
Batson JM
Swager TM
Source :
ACS macro letters [ACS Macro Lett] 2012 Sep 18; Vol. 1 (9), pp. 1121-1123. Date of Electronic Publication: 2012 Aug 27.
Publication Year :
2012

Abstract

We report a versatile new synthetic route to poly( para -phenylene)s (PPPs) and related poly( para -arylene)s containing high degrees of substitution not readily available by other methods. Our method transforms highly soluble, alkyne-containing polymers into PPPs via high-yielding, transition metal-mediated [2+2+2] cyclizations.

Details

Language :
English
ISSN :
2161-1653
Volume :
1
Issue :
9
Database :
MEDLINE
Journal :
ACS macro letters
Publication Type :
Academic Journal
Accession number :
35607179
Full Text :
https://doi.org/10.1021/mz300352m