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Pd-Catalyzed three-component decarboxylative coupling reactions between alkylidene pyrazolones, allyl carbonates and active methylene compounds.

Authors :
Zhang H
Cai LY
Wang K
Zhao HW
Source :
Organic & biomolecular chemistry [Org Biomol Chem] 2022 Jun 29; Vol. 20 (25), pp. 5115-5124. Date of Electronic Publication: 2022 Jun 29.
Publication Year :
2022

Abstract

Under the catalysis of Pd <subscript>2</subscript> (dba) <subscript>3</subscript> ·CHCl <subscript>3</subscript> /(±)-L5 in THF at room temperature, the three-component decarboxylative coupling reactions among alkylidene pyrazolones, allyl carbonates and active methylene compounds proceeded readily and furnished the desired products in acceptable chemical yields. The chemical architecture of the obtained products was unambiguously confirmed by single crystal X-ray analysis.

Details

Language :
English
ISSN :
1477-0539
Volume :
20
Issue :
25
Database :
MEDLINE
Journal :
Organic & biomolecular chemistry
Publication Type :
Academic Journal
Accession number :
35703433
Full Text :
https://doi.org/10.1039/d2ob00791f