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Integrating single Co sites into crystalline covalent triazine frameworks for photoreduction of CO 2 .
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Jul 19; Vol. 58 (58), pp. 8121-8124. Date of Electronic Publication: 2022 Jul 19. - Publication Year :
- 2022
-
Abstract
- Bipyridine-containing covalent triazine framework (CTF-Bpy) was used to prove that the single site distribution of Co <superscript>2+</superscript> was possible. The Co <superscript>2+</superscript> -loaded CTF-Bpy-Co produced 120 μmol CO with a selectivity of 83.8% over 10 h of irradiation (>420 nm). This work highlights the promising potential of single metal sites loaded with CTFs for photocatalytic CO <subscript>2</subscript> reduction.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 58
- Issue :
- 58
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 35771189
- Full Text :
- https://doi.org/10.1039/d2cc02481k