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CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2022 Sep 26; Vol. 51 (37), pp. 14059-14063. Date of Electronic Publication: 2022 Sep 26. - Publication Year :
- 2022
-
Abstract
- A new cesium hydroxyborate CsB <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> , was designed and synthesized by a hydrothermal method. Remarkably, CsB <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> presents novel [B <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> ] <subscript>∞</subscript> chains formed by [B <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> ] fundamental building blocks (FBBs). The report of less common [B <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> ] FBBs and [B <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> ] <subscript>∞</subscript> chains in CsB <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> enriches the structural diversity of hydroxyborates. In addition, CsB <subscript>3</subscript> O <subscript>4</subscript> (OH) <subscript>2</subscript> has a wide transparent window in the DUV spectral range and a large birefringence.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 51
- Issue :
- 37
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 36111778
- Full Text :
- https://doi.org/10.1039/d2dt02573f