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Fabrication of a counter electrode for dye-sensitized solar cells (DSSCs) using a carbon material produced with the organic ligand 2-methyl-8-hydroxyquinolinol (Mq).

Authors :
Kumar R
Sahajwalla V
Bhargava P
Source :
Nanoscale advances [Nanoscale Adv] 2019 Jun 27; Vol. 1 (8), pp. 3192-3199. Date of Electronic Publication: 2019 Jun 27 (Print Publication: 2019).
Publication Year :
2019

Abstract

Dye sensitized solar cells (DSSCs) are low cost solar cells and their fabrication process is easy relative to silicon based solar cells. Platinum can be replaced with carbon materials as counter electrodes in DSSCs because of their good catalytic properties and low cost. A carbon material was produced by carbonization of an organic ligand (2 methyl 8-hydroxy quinolinol (Mq)) at high temperature in flowing argon gas. Polyvinylpyrrolidone (PVP) was used as a surfactant for making carbon slurry from carbon produced using Mq. For the fabrication of the counter electrode, a carbon coating was prepared by using the doctor blading technique and the carbon slurry was coated on the FTO substrate. DSSCs based on the carbon counter electrode exhibit a higher V <subscript>oc</subscript> of 0.75 V than that of the Pt counter electrode (0.69 V). DSSCs based on the carbon material showed a power conversion efficiency (PCE) of 4.25% and fill factor (FF) of 0.51 which are slightly lower than those of the platinum (Pt) based counter electrode which showed a PCE of 5.86% and FF of 0.68.<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © The Royal Society of Chemistry.)

Details

Language :
English
ISSN :
2516-0230
Volume :
1
Issue :
8
Database :
MEDLINE
Journal :
Nanoscale advances
Publication Type :
Academic Journal
Accession number :
36133623
Full Text :
https://doi.org/10.1039/c9na00206e