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Fe 3 O 4 -Halloysite Nanotube Composites as Sustainable Adsorbents: Efficiency in Ofloxacin Removal from Polluted Waters and Ecotoxicity.
- Source :
-
Nanomaterials (Basel, Switzerland) [Nanomaterials (Basel)] 2022 Dec 06; Vol. 12 (23). Date of Electronic Publication: 2022 Dec 06. - Publication Year :
- 2022
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Abstract
- The present work aimed at decorating halloysite nanotubes (HNT) with magnetic Fe <subscript>3</subscript> O <subscript>4</subscript> nanoparticles through different synthetic routes (co-precipitation, hydrothermal, and sol-gel) to test the efficiency of three magnetic composites (HNT/Fe <subscript>3</subscript> O <subscript>4</subscript> ) to remove the antibiotic ofloxacin (OFL) from waters. The chemical-physical features of the obtained materials were characterized through the application of diverse techniques (XRPD, FT-IR spectroscopy, SEM, EDS, and TEM microscopy, thermogravimetric analysis, and magnetization measurements), while ecotoxicity was assessed through a standard test on the freshwater organism Daphnia magna . Independently of the synthesis procedure, the magnetic composites were successfully obtained. The Fe <subscript>3</subscript> O <subscript>4</subscript> is nanometric (about 10 nm) and the weight percentage is sample-dependent. It decorates the HNT's surface and also forms aggregates linking the nanotubes in Fe <subscript>3</subscript> O <subscript>4</subscript> -rich samples. Thermodynamic and kinetic experiments showed different adsorption capacities of OFL, ranging from 23 to 45 mg g <superscript>-1</superscript> . The kinetic process occurred within a few minutes, independently of the composite. The capability of the three HNT/Fe <subscript>3</subscript> O <subscript>4</subscript> in removing the OFL was confirmed under realistic conditions, when OFL was added to tap, river, and effluent waters at µg L <superscript>-1</superscript> concentration. No acute toxicity of the composites was observed on freshwater organisms. Despite the good results obtained for all the composites, the sample by co-precipitation is the most performant as it: (i) is easily magnetically separated from the media after the use; (ii) does not undergo any degradation after three adsorption cycles; (iii) is synthetized through a low-cost procedure. These features make this material an excellent candidate for removal of OFL from water.
Details
- Language :
- English
- ISSN :
- 2079-4991
- Volume :
- 12
- Issue :
- 23
- Database :
- MEDLINE
- Journal :
- Nanomaterials (Basel, Switzerland)
- Publication Type :
- Academic Journal
- Accession number :
- 36500953
- Full Text :
- https://doi.org/10.3390/nano12234330