Flexible stretchable low-energy X-ray (30-80 keV) radiation shielding material: Low-melting-point Ga 1 In 1 Sn 7 Bi 1 alloy/thermoplastic polyurethane composite.

A highly flexible stretchable thermoplastic polyurethane (TPU) composite loaded with a low-melting-point Ga ₁ In ₁ Sn ₇ Bi ₁ multiprincipal element alloy (LMPEA) was prepared, and its radiation shielding performance was evaluated. The fluid characteristic of LMPEA and the flexibility of TPU enable good interface compatibility. Ga ₁ In ₁ Sn ₇ Bi ₁ LMPEA consists of two eutectic structures, and the liquid gallium-rich phases are distributed at the boundary of the InBi intermetallic compound and Sn solid solution. In the low-photon energy range of 30-80 keV, LMPEA has a theoretical specific lead equivalent of 0.803 mmPb/mm and a theoretical weight reduction of 17.27% compared with lead. To evaluate the photon attenuation capability for the LMPEA/TPU composites, the Phy-X procedure and Monte Carlo simulations were used to determine the shielding parameters, such as the mass attenuation coefficient, linear attenuation coefficient, half-value layer, tenth-value layer, mean free path, effective atomic number, and fast neutron removal cross section. The attenuation performance test of X-ray protective materials measured the actual lead equivalent. At the same thickness, the LMPEA/TPU composite (66.667, 50.000 wt% LMPEA loading) has a higher measured lead equivalent than the in-service medical shielding materials, which meets the lead equivalent requirements of X-ray protective clothing. LMPEA/TPU composites are nontoxic, lightweight, and have excellent low-energy X-ray shielding ability, offering great potential for application in medical wearable materials.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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