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Iron-Catalyzed, Directed Benzylic Borylation.
- Source :
-
Organic letters [Org Lett] 2023 Jan 13; Vol. 25 (1), pp. 1-4. Date of Electronic Publication: 2022 Dec 22. - Publication Year :
- 2023
-
Abstract
- Herein, we describe an iron-catalyzed benzylic C-H borylation reaction. The reaction targets primary and secondary C(sp <superscript>3</superscript> )-H bonds to deliver high-value boronic esters under mild conditions with short (7-8 min) reaction times. Functional groups are well tolerated, and complete site selectivity is observed in the presence of multiple benzylic C-H bonds.
- Subjects :
- Catalysis
Boron chemistry
Iron chemistry
Esters chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 25
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 36550075
- Full Text :
- https://doi.org/10.1021/acs.orglett.2c02864